Download e-book for kindle: Advanced Organic Chemistry: Part B: Reactions and Synthesis by Francis A. Carey

By Francis A. Carey

ISBN-10: 0306434571

ISBN-13: 9780306434570

ISBN-10: 1461397979

ISBN-13: 9781461397977

The two-part, 5th variation of complicated natural Chemistry has been considerably revised and reorganized for better readability. the fabric has been up to date to mirror advances within the box because the prior variation, in particular in computational chemistry. half B describes the main common and helpful man made reactions, geared up at the foundation of response sort. it will possibly stand-alone; jointly, with half A: constitution and Mechanisms, the 2 volumes supply a finished beginning for the learn in natural chemistry. spouse web content offer electronic versions for college kids and workout suggestions for instructors.

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Extra info for Advanced Organic Chemistry: Part B: Reactions and Synthesis

Sample text

4 lists some examples that have been reported. 64 The interpretation and prediction of the relationship between the configuration of the newly formed chiral center and the configuration of the amine is usually based on steric differentiation of the two faces of the azaallyl anion. Most imine anions which show high stereoselectivity incorporate a substituent which can hold the metal cation in a compact transition state by chelation. 4, for example, the transition state G rationalizes the observed enantioselectivity.

R. Dunnavant, Orr. Synth. IV, 962 (l963). E. M. Kaiser, W. O. Kenyon, and C. R. Hauser, Org. Synth. 47, 72 (l967). R. P. Mariella and R. Raube, Org. Synth. IV, 288 (l963). K. F. Bernardy, J. F. Paletta, J. Nocera, P. Miranda, R. E. Schaub, and M. J. Weiss, 1. Org. Chern. 45, 4702 (1980). is the desired product. 4. This example illustrates the synthesis of cyclic compounds by intramolecular alkylation reactions. 5. Synthesis of Ketones and Carboxylic Acid Derivatives via Alkylation Techniques I" CHJCOCHCOzCzH s I 'f CHJCOCHCOi" H,O.

G. Rondan, R. R. Frazier, and N. Chauqui-Otterrnans, 1. Am. Chern. Soc. 102, 1426 (1980). 63. J. K. Smith, M. Newcomb, D. E. Bergbreiter, D. R. Williams, and A. I. Meyer, Tetrahedron Lett. 24, 3559 (1983); J. K. Smith, D. E. Bergbreiter, and M. Newcomb, 1. Am. Chern. Soc. lOS, 4396 (1983); A. Hosomi, Y. Arak, and H. Sakurai, 1. Am. Chern. Soc. 104, 2081 (1982). 9. THE NITROGEN ANALOGS OF ENOLS AND ENOLATESENAMINES AND IMINE ANIONS 36 CHAPTER I ALKYLATION OF NUCLEOPHILIC CARBON. ENOLATES AND ENAMINES One of the most useful aspects of the imine anions is that they can be readily prepared from enantiomerically pure amines.

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Advanced Organic Chemistry: Part B: Reactions and Synthesis by Francis A. Carey

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